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Thermogravimetric analysis and structure change of lime-pretreated Spartina alterniflora

文献类型: 外文期刊

作者: Liang, Yue-gan 1 ; Cheng, Beijiu 1 ; Liang, Rui 1 ; Chen, Jian-Feng 2 ; Chen, Hua 2 ;

作者机构: 1.Anhui Agr Univ, Sch Life Sci, Key Lab Biomass Improvement & Convers Anhui Prov, Hefei 230036, Peoples R China

2.Yunnan Acad Agr Sci, Agr Environm & Resources Inst, Kunming, Peoples R China

关键词: Kinetic parameter;smooth cordgrass;structure change;thermal behavior

期刊名称:ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS ( 影响因子:3.447; 五年影响因子:2.406 )

ISSN: 1556-7036

年卷期: 2016 年 38 卷 12 期

页码:

收录情况: SCI

摘要: The thermal behavior and structure change of Spartina alterniflora pretreated with lime were investigated with raw and water-soaked samples for comparisons. Pretreatment significantly changed thermal decomposition behavior and activation energy. The activation energy of S. alterniflora ranged from 100.7 to 128 kJ/mol at the main decomposition stage. FTIR and solid-state C-13 NMR analyses revealed that pretreatment disrupted the carboxyl carbons attached to the lignin side chain. Compared with water soaking, lime pretreatment resulted in more modifications of structure and composition. Furthermore, structure breakage and composition removal change the pyrolysis characteristics of pretreated samples.

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[1]Effect of thermo-lime and hot-water pretreatment on the thermal-decomposition characteristics and structure of Spartina alterniflora. Liang, Yue-Gan,Cheng, Bei-Jiu,Jiang, Hai-Yang,Han, Guo-Min,Liang, Yue-Gan,Yin, Shuai-Shuai,Si, You-Bin,Hong, Li-Fang.

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