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Dummy-template molecularly imprinted micro-solid-phase extraction coupled with high-performance liquid chromatography for bisphenol A determination in environmental water samples

文献类型： 外文期刊

作者： Liu, Yuanchen 1 ; Wang, Dan 1 ; Du, Fuyou 2 ; Zheng, Wenqian 1 ; Liu, Zhimin 1 ; Xu, Zhigang 1 ; Hu, Xianzhi 1 ; Liu, Hon 1 ;

作者机构： 1.Kunming Univ Sci & Technol, Fac Sci, Kunming 650500, Yunnan, Peoples R China

2.Guilin Univ Technol, Coll Chem & Bioengn, Guangxi Key Lab Electrochem & Magnetochem Funct M, Guilin 541004, Peoples R China

3.Yunnan Acad Agr Sci, Inst Qual Stand & Testing Technol, Kunming Xufu Rd, Kunming 650223, Yunnan, Peoples R China

关键词： Dummy-template; Molecularly imprinted polymer; Micro-solid-phase extraction; Bisphenol; Water samples; Recognition

期刊名称：MICROCHEMICAL JOURNAL （ 影响因子：4.821； 五年影响因子：4.364 ）

ISSN： 0026-265X

年卷期： 2019 年 145 卷

页码：

收录情况： SCI

摘要： Four dummy templates (bisphenol B, bisphenol F, tetrabromobisphenol A, and 4-tert-butylphenol) were selected as template molecules to prepare a dummy-template molecularly imprinted polymer (MIP) for BPA analysis. The four of dummy-template MIP micro solid phase extraction bars showed good selectivity for bisphenol compounds and could be used to extract SPA present in real water samples. Furthermore, the strong bonding force between dummy-template and 4-vinyl pyridine (4-VP) was further verified by the theoretical calculations. It was found that the difference of the value coming from the system of dummy template and 4-VP was larger than that of BPA with 4-VP, revealing the strongest electronic interactions between the dummy template and 4-VP. Meanwhile, it also reveals that dummy-template MIPs are equally effective and even stronger in bonding bisphenol in complex samples. The dummy-template MIP micro solid phase extraction bars were suitable for trace BPA analysis in water samples without being affected by template leakage. The recoveries of SPA from pond water and sewage samples were 65.56-88.84% with the relative standard deviation of 1.30-8.93%. The linear range was 0.01-15 mu g.L-1 (r(2) = 0.9998). The limit of detection was 0.003 mu g.L-1 (signal-to-noise ratio (S/N = 3)). The limit of quantification, which was the lowest concentration that could be quantitatively detected, was found to be 0.01 mu g.L-1 (S/N = 10). The proposed sample preparation method is easy, simple, and reproducible.

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