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Diversity of chemiluminescence from fluoroquinolones in the presence of peroxynitrous acid

文献类型： 外文期刊

作者： Wei, Lijun 1 ; Liu, Jing 1 ; Liu, Hongcheng 2 ; Zhou, Tong 1 ; Cai, Hongping 1 ; Cheng, Xianglei 1 ;

作者机构： 1.Nanchang Univ, Sch Publ Hlth, 461 Bayi Rd, Nanchang 330006, Peoples R China

2.Yunnan Acad Agr Sci, Inst Qual Standard & Testing Technol, Kunming 650223, Peoples R China

关键词： Chemiluminescence;Diversity;Fluoroquinolones;Peroxynitrous acid;Defluorination

期刊名称：JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY （ 影响因子：4.291； 五年影响因子：3.854 ）

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收录情况： SCI

摘要： In this article, eight fluoroquinolone analogs showed intriguing chemiluminescence (CL) diversity in the presence of peroxynitrous acid. Compared to current literature, these studied fluoroquinolones exhibit many novel characteristics on CL spectra, CL quantum yield and reaction routes. Furthermore, when the distribution of CL was comparable to its fluorescence, a diversity of differences between the analogs were observed. These results indicate that the hydroxyl radical (OH)-O-center dot and excited state peroxynitrous acid may account for these observations. This discovery could deepen the understanding of mechanisms in CL systems and change the traditional theories about CL phenomena. (C) 2016 Elsevier B.V. All rights reserved.

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